Intermetallics ( IF 4.3 ) Pub Date : 2022-06-18 , DOI: 10.1016/j.intermet.2022.107613 S.V. Malik , E.T. Dias , V. Srihari , P.D. Babu , K.R. Priolkar
A systematic investigation of the structure and local structure of Ni2−xMn1+xGa alloys 0 ≤ x ≤ 1 reveals antisite disorder to be a possible reason for higher martensitic transformation temperature of Mn2NiGa as compared to Ni2MnGa. The antisite disorder between the Y and Z sublattices of the X2YZ Heusler structure results in segregation of Mn3Ga type defect phase and a Ni-rich Heulser phase with a higher e/a ratio. This Ni-rich Heusler phase appears to be responsible for the higher martensitic transformation temperature of the Mn2NiGa type Heusler alloys.
中文翻译:
反位无序在 Ni2−xMn1+xGa 的马氏体转变中的作用
对 Ni 2− x Mn 1+ x Ga 合金 0 ≤ x ≤ 1的结构和局部结构的系统研究表明,与 Ni 2 MnGa相比,反位无序是 Mn 2 NiGa 的马氏体转变温度更高的可能原因。X 2 YZ Heusler结构的Y和Z亚晶格之间的反位无序导致Mn 3 Ga型缺陷相和具有较高e/a比的富Ni Heulser相偏析。这种富含镍的 Heusler 相似乎是 Mn 2 NiGa 型 Heusler 合金较高的马氏体转变温度的原因。