In this study, we apply the superoxide-assisted electrochemical deposition method to obtain polyporphyrin films based on 2Н-5,10,15,20-tetrakis(3-aminophenyl)porphyrin from dimethylsulfoxide solutions. It is shown that changes in the potential scan rate affect the film formation efficiency and surface morphology of electrodeposited polyporphyrin films. Poly-2H-5,10,15,20-tetrakis(3-aminophenyl)porphyrin films prepared at a given deposition time in low formation efficiency conditions are thinner and smoother. Surface morphology has a considerable effect on the functional properties of a material and scan rate variations can be considered a control parameter for adjusting the formation process to the film target functional application.

在这项研究中，我们应用超氧化物辅助电化学沉积方法从二甲亚砜溶液中获得了基于 2Н-5,10,15,20-四( 3-氨基苯基)卟啉的多卟啉薄膜。结果表明，电位扫描速率的变化会影响电沉积多卟啉薄膜的成膜效率和表面形貌。Poly-2H-5,10,15,20-四( 3-氨基苯基)卟啉薄膜在低形成效率条件下以给定的沉积时间制备更薄、更光滑。表面形态对材料的功能特性有相当大的影响，扫描速率变化可以被认为是调整形成过程以适应薄膜目标功能应用的控制参数。