The corrosion, parasitic side-reaction and dendrite of Zn anode as well as the dissolution of MnO₂ cathode limit the commercial application of zinc-ion batteries (ZIBs). Herein, a novel coating layer on Zn anode and MnO₂ cathode of rechargeable ZIBs is rationally designed by mixing hexadecyl trimethyl ammonium bromide(CTAB)-pillared organic montmorillonite with ZnSO₄/MnSO₄ solution (ZnOMMT). ZnOMMT can serve as the protective layer to alleviate Zn corrosion and MnO₂ dissolution while the unique interlayer structure of ZnOMMT can also offer a selective pathway for fast Zn²⁺ transfer and uniform Zn²⁺ diffusion to inhibit the side-reaction and Zn dendrite generation. Notably, by the powerful pillaring of CTAB cations, the expanded and robust nanoscale interlayer tunnels of ZnOMMT for Zn²⁺ diffusion are constructed to guarantee outstanding ionic conductivity (6.52 mS cm⁻¹), high Zn²⁺ transference number (t₊=0.66) and outstanding cyclic stability during deep cycles. Therefore, ZIBs with ZnOMMT coating layer deliver a steady long-term reversible capacity (267 mAh g⁻¹ until 300 cycles at 0.5 A g⁻¹, 205 mAh g⁻¹ until 700 cycles at 1.0 A g⁻¹). The rational design of CTAB-pillared montmorillonite protective layer brings a brand-new opportunity to the realization of high-performance rechargeable ZIBs.

锌负极的腐蚀、寄生副反应和枝晶以及MnO ₂正极的溶解限制了锌离子电池（ZIBs）的商业应用。在此，通过将十六烷基三甲基溴化铵（CTAB）柱柱有机蒙脱土与ZnSO ₄ /MnSO ₄溶液（ZnOMMT）混合，合理设计了可充电ZIBs的Zn阳极和MnO ₂阴极上的新型涂层。ZnOMMT 可以作为保护层来缓解 Zn 腐蚀和 MnO ₂溶解，而 ZnOMMT 独特的层间结构还可以为快速 Zn ²⁺转移和均匀 Zn ^{2+提供选择性途径}扩散以抑制副反应和锌枝晶的生成。值得注意的是，通过CTAB阳离子的强大支柱，ZnOMMT的扩展和坚固的纳米级层间隧道用于Zn ²⁺扩散，以保证出色的离子电导率（6.52 mS cm ^-1），高Zn ²⁺迁移数（t ₊ =0.66 ) 和在深循环期间出色的循环稳定性。因此，具有 ZnOMMT 涂层的 ZIB 可提供稳定的长期可逆容量（267 mAh g ^-1在 0.5 A g ^{-1下循环 300 次，在 1.0 A g -1}下循环205 mAh g ^-1直到 700 次））。CTAB柱蒙脱石保护层的合理设计为高性能可充电ZIBs的实现带来了全新的机遇。