Journal of Quantitative Spectroscopy and Radiative Transfer ( IF 2.3 ) Pub Date : 2022-06-16 , DOI: 10.1016/j.jqsrt.2022.108295 Charles A. Bowesman , Hanieh Akbari , W.Scott. Hopkins , Sergei N. Yurchenko , Jonathan Tennyson
A MARVEL (measured active rotational-vibrational energy levels) analysis of the spectra of vanadium oxide (VO) is performed, involving thirteen electronic states (6 quartets and 7 doublets). VO data from 14 sources are used to form three networks: hyperfine-resolved quartets, hyperfine-unresolved quartets and hyperfine-unresolved doublets. A single quartet network is formed by deperturbing the hyperfine lines and 191 lines are assigned to an intercombination 2 –X band system in the visible region previously recorded by Hopkins et al. (J. Chem. Phys. 130 (2009) 144308), allowing the doublet and quartet networks to be merged. As a result 6 603/4 402 validated transitions/final energies were obtained from analysis of the hyperfine-resolved network and 9 087/4 712 from the unresolved. energy values and other molecular constants are determined for all doublet states within the networks.
中文翻译:
精细和超精细分辨VO的经验能级
对氧化钒 (VO) 的光谱进行了 MARVEL(测量的主动旋转振动能级)分析,涉及 13 个电子态(6 个四重态和 7 个双重态)。五来自 14 个来源的 O 数据用于形成三个网络:超精细解析四重奏、超精细未解析四重奏和超精细未解析双联。通过对超细线的扰动形成一个单一的四重奏网络,191 条线被分配给一个相互组合 2 -X 霍普金斯等人先前记录的可见区域中的波段系统。(J. Chem. Phys. 130 (2009) 144308),允许合并双联和四联网络。结果,从超精细分辨网络的分析中获得了 6 603/4 402 个经过验证的跃迁/最终能量,从未分辨的网络中获得了 9 087/4 712 个。为网络内的所有双线态确定能量值和其他分子常数。