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Fluorescent cyclophanes and their applications
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2022-06-15 , DOI: 10.1039/d0cs00352b
Indranil Roy 1 , Arthur H G David 1 , Partha Jyoti Das 1 , David J Pe 1 , J Fraser Stoddart 1, 2, 3, 4
Affiliation  

With the serendipitous discovery of crown ethers by Pedersen more than half a century ago and the subsequent introduction of host–guest chemistry and supramolecular chemistry by Cram and Lehn, respectively, followed by the design and synthesis of wholly synthetic cyclophanes—in particular, fluorescent cyclophanes, having rich structural characteristics and functions—have been the focus of considerable research activity during the past few decades. Cyclophanes with remarkable emissive properties have been investigated continuously over the years and employed in numerous applications across the field of science and technology. In this Review, we feature the recent developments in the chemistry of fluorescent cyclophanes, along with their design and synthesis. Their host–guest chemistry and applications related to their structure and properties are highlighted.

中文翻译:

荧光环烷及其应用

半个多世纪前,Pedersen 偶然发现冠醚,随后分别由 Cram 和 Lehn 引入主客体化学和超分子化学,随后设计和合成了全合成环烷,特别是荧光环烷,具有丰富的结构特征和功能——一直是过去几十年大量研究活动的焦点。多年来,人们不断研究具有显着发射特性的环烷,并在科学和技术领域的众多应用中得到应用。在这篇评论中,我们介绍了荧光环烷化学的最新进展,以及它们的设计和合成。
更新日期:2022-06-15
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