Construction and application of base-stable MOFs: a critical review,Chemical Society Reviews

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Construction and application of base-stable MOFs: a critical review
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2022-06-15 , DOI: 10.1039/d1cs00891a
Kecheng Wang ₁ , Yaping Li _{1,

2} , Lin-Hua Xie ₁ , Xiangyu Li ₁ , Jian-Rong Li ₁

Affiliation

Metal–organic frameworks (MOFs) are a new class of porous crystalline materials constructed from organic ligands and metal ions/clusters. Owing to their unique advantages, they have attracted more and more attention in recent years and numerous studies have revealed their great potential in various applications. Many important applications of MOFs inevitably involve harsh alkaline operational environments. To achieve high performance and long cycling life in these applications, high stability of MOFs against bases is necessary. Therefore, the construction of base-stable MOFs has become a critical research direction in the MOF field. This review gives a historic summary of the development of base-stable MOFs in the last few years. The key factors that can determine the robustness of MOFs under basic conditions are analyzed. We also demonstrate the exciting achievements that have been made by utilizing base-stable MOFs in different applications. In the end, we discuss major challenges for the further development of base-stable MOFs. Some possible methods to address these problems are presented.

中文翻译：

基稳定 MOF 的构建和应用：批判性审查

金属有机骨架（MOFs）是一类由有机配体和金属离子/簇构成的新型多孔结晶材料。由于其独特的优势，近年来它们越来越受到关注，大量研究表明它们在各种应用中的巨大潜力。MOF 的许多重要应用不可避免地涉及恶劣的碱性操作环境。为了在这些应用中实现高性能和长循环寿命，MOF 对碱的高稳定性是必要的。因此，构建基稳MOFs已成为MOF领域的重要研究方向。这篇综述对过去几年中基稳定 MOF 的发展进行了历史性总结。分析了在基本条件下决定MOFs鲁棒性的关键因素。我们还展示了通过在不同应用中使用基稳定 MOF 所取得的令人兴奋的成就。最后，我们讨论了基稳定 MOF 进一步发展的主要挑战。提出了一些可能的方法来解决这些问题。

更新日期：2022-06-15

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