当前位置: X-MOL 学术Electrochim. Acta › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Enhancing electrochemical performance of fluorinated graphite by polydopamine−derived nitrogen−doped carbon coating
Electrochimica Acta ( IF 5.5 ) Pub Date : 2022-06-13 , DOI: 10.1016/j.electacta.2022.140718
Caifeng Zhu , Xiangyan Shen , Zifeng Gao , Yanyan Li , Xiaozhong Wu , Jinping Zhao , Pengfei Zhou , Shuping Zhuo , Jin Zhou

The poor electronic conductivity of fluorinated graphite (CFx) is one of the key problems limiting its electrochemical performance. Herein, polydopamine−derived nitrogen−doped carbon coating is adapted to improve the electrochemical performance of CFx by modifying its electronic conductivity. The effects of dopamine hydrochloride/CFx ratio and the carbonization temperature on the electrochemical performance of nitrogen−doped carbon coated CFx samples (CFx@NC−x−y) cathodes are investigated. CFx@NC−x−y cathodes present enhanced rate performance and discharge plateau, and increased energy and power densities, compared with the pristine CFx. Particularly, the CFx@NC−3−350 achieves optimized electrochemical performance, such as a discharge capacity of 550.5 mAh g−1 with a plateau of 2.18 V at 2000 mA g−1, corresponding to high power and energy densities of 4360 W kg−1 and 1171.2 Wh kg−1, whereas the pristine CFx is unable to work. The enhanced electrochemical performance is contributed to the improved electronic conductivity of the nitrogen−doped carbon−coated CFx.



中文翻译:

聚多巴胺衍生的氮掺杂碳涂层提高氟化石墨的电化学性能

氟化石墨(CF x)较差的电子导电性是限制其电化学性能的关键问题之一。在此,聚多巴胺衍生的氮掺杂碳涂层适用于通过改变其电子电导率来提高 CF x的电化学性能。研究了多巴胺盐酸盐/CF x比率和碳化温度对氮掺杂碳涂层 CF x样品(CF x @NC-x-y)阴极电化学性能的影响。与原始 CF x相比, CF x @NC-x-y 正极具有更高的倍率性能和放电平台,以及更高的能量和功率密度. 特别是,CF x @NC-3-350 实现了优化的电化学性能,例如放电容量为 550.5 mAh g -1,在 2000 mA g -1下具有 2.18 V 的平台,对应于 4360 W 的高功率和能量密度kg -1和 1171.2 Wh kg -1,而原始 CF x无法工作。增强的电化学性能有助于提高氮掺杂碳涂层CF x的电子电导率。

更新日期:2022-06-13
down
wechat
bug