Ruthenium-catalyzed meta-difluoromethylation of arene phosphines enabled by 1,3-dione,Organic Chemistry Frontiers

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Ruthenium-catalyzed meta-difluoromethylation of arene phosphines enabled by 1,3-dione
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2022-06-14 , DOI: 10.1039/d2qo00666a
Wen-Qian Xu ₁ , Jun-Yang Tao ₁ , Yue-Jin Liu ₁ , Ming-Hua Zeng _{1,

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Affiliation

A highly efficient, meta-selective difluoromethylation of arene phosphines has been developed with ruthenium catalysis using 1,3-dione as an effective ligand. A wide variety of biarylphosphines bearing various functional groups were all compatible with the reaction conditions, leading to meta-difluoromethylated phosphine products in moderate to good yields.

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