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Palladium-Catalyzed Synthesis of Carbazoles by Perester
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2022-06-13 , DOI: 10.1002/adsc.202200419
Li He 1 , Yongjun Xu 1
Affiliation  

An intramolecular C−H amination for the synthesis of carbazoles with a Pd(II)/TBPB system has been developed. This catalytic amination process forms the carbazole products in good to excellent yields. It is noteworthy that this method implied the advantages of the catalytic mode involving perester with transition metal catalyst in the activation of inert C−H bonds. In addition, the transformation performs well using water as solvent.

中文翻译:

Perester 钯催化合成咔唑

已经开发了一种用于合成咔唑的分子内 C-H 胺化 Pd(II)/TBPB 系统。这种催化胺化过程以良好至极好的收率形成咔唑产物。值得注意的是,该方法暗示了过酸酯与过渡金属催化剂在惰性C-H键活化中的催化模式的优势。此外,使用水作为溶剂,转化效果很好。
更新日期:2022-06-13
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