In this paper, we present a MoP/P–Mn_0.5Cd_0.5S photocatalytic material (PMOMCS-Px). A novel catalyst can efficiently split water into hydrogen without precious metals. In the sacrificial agent environment, the HER (hydrogen evolution rate) of PMOMCS-P5 was 4368.25 μmol g⁻¹ h⁻¹ which was 11.4 times greater than the HER of Mn_0.5Cd_0.5S (383.19 μmol g⁻¹ h⁻¹), and its hydrogen production performance was better than that of Pt/Mn_0.5Cd_0.5S (2.0 wt% Pt). Furthermore, the hydrogen evolution performance of PMOMCS-P5 under pure water conditions was also examined, and the HER of PMOMCS-P5 was 209.76 μmol g⁻¹ h⁻¹, which was 20.4 times that of Mn_0.5Cd_0.5S (10.29 μmol g⁻¹ h⁻¹). Its characterization proved that the introduction of the co-catalyst MoP and P doping inhibited the recombination of e⁻ and h⁺, enhanced the reduction capacity, and reduced the hydrogen precipitation reaction overpotential of PMOMCS-Px, thus enhancing the hydrogen production performance of PMOMCS-Px. Therefore, an efficient and economical photocatalyst was prepared.

中文翻译：

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0D/0D MoP改性P掺杂Mn0.5Cd0.5S光催化剂显着提高析氢性能

在本文中，我们提出了一种 MoP/P-Mn _0.5 Cd _0.5 S 光催化材料 (PMOMCS-P x )。一种新型催化剂可以在没有贵金属的情况下有效地将水分解成氢气。在牺牲剂环境下，PMOMCS-P5的HER（析氢速率）为4368.25 μmol g ^-1 h ^{-1 ，是Mn} _0.5 Cd _0.5 S的HER（383.19 μmol g ^-1 h ^-1）的11.4倍, 其制氢性能优于 Pt/Mn _0.5 Cd _0.5S (2.0 wt% Pt)。此外，还考察了PMOMCS-P5在纯水条件下的析氢性能，PMOMCS-P5的HER为209.76 μmol g ^-1 h ^-1，是Mn _0.5 Cd _0.5 S（10.29 μmol g ）的20.4倍。 ^-1 h ^-1 )。其表征证明，助催化剂 MoP 和 P 掺杂的引入抑制了 e ^-和 h ⁺的复合，增强了还原能力，降低了 PMOMCS-P x的析氢反应过电位，从而提高了产氢性能。 PMOMCS-P x. 因此，制备了一种高效且经济的光催化剂。