当前位置: X-MOL 学术Polymer › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Fluorene based electrochromic conjugated polymers: A review
Polymer ( IF 4.1 ) Pub Date : 2022-06-10 , DOI: 10.1016/j.polymer.2022.125040
Buket Bezgin Carbas

This review briefly describes electrochromic conductive polymers containing fluorene in the main chain or as a subunit/core. According to the arrangement of the fluorene unit and its chemical location on the chain, polyfluorene family was expressed in three classes; fluorene EC homopolymers, copolymers and functional EC polymers. With its sometimes surprising properties and countless advantages, fluorene monomer has many contributions to the electrochromic conductive polymer chain. Although there are many fluorene derived polymers in the literature that have been functionalized and/or used in various applications, this review only found it appropriate to focus on conductive electrochromic polymers with possessing fluorene chemical units. For this purpose, it has been tried to review and comment on fluorene polymers by comparing their chemical, electrochemical and optical properties in a logical framework. One of the biggest problems of electrochromic conductive polymer researchers is to analyze how the redox and electrochromic properties of polymers, which consist of a functional group, change according to the position on the conjugated polymer chain. For this reason, it is thought that the contribution and guideness of this study to the literature will be considerable.



中文翻译:

芴基电致变色共轭聚合物:综述

这篇综述简要介绍了在主链中或作为亚基/核心含有芴的电致变色导电聚合物。根据芴单元的排列方式及其在链上的化学位置,聚芴家族分为三类;芴 EC 均聚物、共聚物和功能性 EC 聚合物。芴单体以其有时令人惊讶的特性和无数的优势,对电致变色导电聚合物链做出了许多贡献。尽管文献中有许多芴衍生聚合物已被功能化和/或用于各种应用,但本综述发现仅关注具有芴化学单元的导电电致变色聚合物是合适的。为此,已尝试通过比较芴聚合物的化学成分来审查和评论芴聚合物,逻辑框架中的电化学和光学性质。电致变色导电聚合物研究人员面临的最大问题之一是分析由官能团组成的聚合物的氧化还原和电致变色性质如何根据共轭聚合物链上的位置而变化。因此,认为本研究对文献的贡献和指导意义将是相当大的。

更新日期:2022-06-10
down
wechat
bug