A Three-Way Regioselective Synthesis of Amino Acid Decorated Imidazole, Purine and Pyrimidine Derivatives by Multicomponent Chemistry Starting from Prebiotic Diaminomaleonitrile,European Journal of Organic Chemistry

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A Three-Way Regioselective Synthesis of Amino Acid Decorated Imidazole, Purine and Pyrimidine Derivatives by Multicomponent Chemistry Starting from Prebiotic Diaminomaleonitrile
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-06-10 , DOI: 10.1002/ejoc.202200598
Bruno Mattia Bizzarri ₁ , Angelica Fanelli ₂ , Silvia Cesarini ₂ , Raffaele Saladino ₂

Affiliation

Regioselectivity of the multicomponent reaction between diaminomaleonitrile, trimethyl orthoacetate and α-amino acids, controlled by the energy source. Imidazoles are obtained under thermal condition, pyrimidines under photochemical conditions while purines by applying photothermal conditions.

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