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Corrigendum: Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C–H Bonds via Reversible η6-Coordination
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-06-10 , DOI: 10.1002/anie.202203820
Qi‐Kai Kang , Yuntong Li , Kai Chen , Hui Zhu , Wen‐Qiang Wu , Yunzhi Lin , Hang Shi

The authors have found that the ss values (the percentage of the reaction that proceeds with stereoretention) of compounds 56 to 64 in Table 3 are different from those given in the Supporting Information, which are correct. Corrections to the Reference section are also required, as described below.

The ss values of 56 to 64 in Table 3 of this Research Article should be corrected as follows: compound 56, >98% ss; 57, >95% ss; 58, 93% ss; 59, >95% ss; 60, >95% ss; 61, >95% ss; 62, >95% ss; 63, >95% ss; 64, 94% ss.

Reference 22 should read “Prolonging the reaction time would decrease stereoretention. For example: see detailed labeling experiments of 58 and 64 in the Supporting Information.”

For the deprotonation of unbiased benzylic C−H bonds by KOtBu/LiTMP, important work reported by Fleming and O′Shea should be cited.1 For the stereoretentive reaction via a Cr(CO)3-stabilized benzylic anion, the work of Gibson, Schmalz, Koning, and co-workers should be cited.2

The authors sincerely apologize for any inconvenience caused by these corrections. This Corrigendum has no impact on the conclusion of the article.



中文翻译:

勘误:通过可逆 η6-配位的铑催化的苄基 C-H 键的立体选择性氘化

作者发现表 3 中化合物5664的 ss 值(以立体保留进行的反应的百分比)与支持信息中给出的值不同,这是正确的。如下所述,还需要对参考部分进行更正。

本研究论文表 3 中5664的 ss 值应修正如下:化合物56,>98% ss;57 , >95% ss; 58 , 93% 不锈钢; 59 , >95% ss; 60 , >95% ss; 61 , >95% ss; 62 , >95% ss; 63 , >95% ss; 64 , 94% 不锈钢。

参考文献 22 应为“延长反应时间会降低立体保持力。例如:参见支持信息中58​​ 和64的详细标记实验。”

对于 KO t Bu/LiTMP 对无偏苄基 C-H 键的去质子化,应引用 Fleming 和 O'Shea 报告的重要工作。1对于通过 Cr(CO) 3稳定的苄基阴离子的立体保留反应,应引用 Gibson、Schmalz、Koning 和同事的工作。2

作者对这些更正造成的任何不便表示诚挚的歉意。本勘误对文章的结论没有影响。

更新日期:2022-06-10
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