Formal total synthesis of dankasterone B,Organic Chemistry Frontiers

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Formal total synthesis of dankasterone B
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2022-06-10 , DOI: 10.1039/d2qo00299j
Shengzhen Deng ₁ , Hongjin Xu ₁ , Huanfeng Jiang ₁ , Zhiqiang Ma ₁

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An efficient and enantioselective route toward an architecturally unusual ergostane-type steroid, dankasterone B, is presented. The cis-decalin skeleton of the steroid was established by an intramolecular metal-catalyzed hydrogen atom transfer (MHAT) reaction. A radical rearrangement was used to construct the 13(14 → 8)abeo-ergostane skeleton.

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