Site-Selective Functionalization of Carboranes at the Electron-Rich Boron Vertex: Photocatalytic B−C Coupling via a Carboranyl Cage Radical,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Site-Selective Functionalization of Carboranes at the Electron-Rich Boron Vertex: Photocatalytic B−C Coupling via a Carboranyl Cage Radical
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-07 , DOI: 10.1002/anie.202205672
Meng Chen ₁ , Jingkai Xu ₁ , Deshi Zhao ₁ , Fangxiang Sun ₁ , Songlin Tian ₁ , Deshuang Tu ₁ , Changsheng Lu ₁ , Hong Yan ₁

Affiliation

A new photocatalytic strategy for the site-selective functionalization of carboranes was demonstrated by the photo-induced decarboxylation of carborane carboxylic acids to generate boron-vertex-centered carboranyl radicals. This strategy enables facile construction of highly efficient blue emitters and drug candidates for boron neutron capture therapy (BNCT).

中文翻译：