Rh(III)-Catalyzed C–C coupling of unactivated C(sp3)–H bonds with iodonium ylides for accessing all-carbon quaternary centers,Organic Chemistry Frontiers

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Rh(III)-Catalyzed C–C coupling of unactivated C(sp3)–H bonds with iodonium ylides for accessing all-carbon quaternary centers
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2022-06-07 , DOI: 10.1039/d2qo00667g
Pengfei Xie ₁ , Huixing Gao ₁ , Xingwei Li ₁ , Yuqin Jiang ₁ , Bingxian Liu ₁

Affiliation

Rhodium-catalyzed inert C(sp³)–H activation/carbene insertion, which enables the construction of all-carbon quaternary centers, has been realized. Iodonium ylides are used as C1 synthons for efficient C–C bond formation with PhI being the only by-product. A rhodacycle has been synthesized and proved to be the active intermediate.

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