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Base-Promoted Reaction of Phenols with Spirocylic λ3-Iodanes: Access to Both 2-Iodovinyl Aryl Ethers and Diaryl Ethers
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-06-05 , DOI: 10.1002/ejoc.202200516
Shun-Dong He 1 , Xiao-Qiang Guo 2 , Jun Li 2 , Yu-Cheng Zhang 2 , Lian-Mei Chen 3 , Tai-Ran Kang 4
Affiliation  

An efficient method for vinyl or aryl C(sp2)−O bond formation to construct both (Z)-2-iodovinyl aryl ethers and diaryl ethers through a reactivity between spiro-EBXs and phenols under metal-, photocatalyst- and light-free conditions has been developed.

中文翻译:

苯酚与螺环 λ3-碘烷的碱促进反应:获得 2-碘乙烯基芳基醚和二芳基醚

一种有效的乙烯基或芳基 C(sp 2 )-O 键形成方法,通过螺-EBX 和酚在金属、光催化剂和无光下的反应性构建 ( Z )-2-碘乙烯基芳基醚和二芳基醚条件已经形成。
更新日期:2022-06-05
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