A novel copper metal–organic framework catalyst for the highly efficient conversion of CO2 with propargylic amines,Inorganic Chemistry Frontiers

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A novel copper metal–organic framework catalyst for the highly efficient conversion of CO2 with propargylic amines
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2022-06-06 , DOI: 10.1039/d2qi00678b
Xiao Xu ₁ , Zhentao Li ₁ , Huilin Huang ₁ , Xu Jing ₁ , Chunying Duan ₁

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The rapid increase in atmospheric carbon dioxide has resulted in the greenhouse effect. Hence, carbon dioxide capture and further fixation into valuable chemical products are particularly important for reducing atmospheric carbon dioxide concentrations. In this direction, a novel copper-based metal three-dimensional framework, Cu-TSP, was assembled from tripod ligands containing thiourea groups; this heterogeneous material can efficiently catalyze the reaction of propargylic amines and carbon dioxide to synthesize 2-oxazolidinones, and the recyclability and high conversion rates demonstrate the broad potential applications of this designed material as a π-activated catalyst in the chemical industry.

中文翻译：

一种新型铜金属有机骨架催化剂，用于高效转化 CO2 与炔丙基胺

大气中二氧化碳的快速增加导致了温室效应。因此，二氧化碳捕获和进一步固定在有价值的化学产品中对于降低大气中的二氧化碳浓度特别重要。在这个方向上，一种新型的铜基金属三维骨架 Cu- TSP由含有硫脲基团的三脚架配体组装而成；这种非均相材料可以有效地催化炔丙基胺和二氧化碳反应合成 2-恶唑烷酮，其可回收性和高转化率证明了这种设计的材料在化学工业中作为 π 活化催化剂的广泛潜在应用。

更新日期：2022-06-06

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