Low-Voltage-Driven Electrochemical Aerobic Oxygenation with Flavin Catalysis: Chemoselective Synthesis of Sulfoxides from Sulfides,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Low-Voltage-Driven Electrochemical Aerobic Oxygenation with Flavin Catalysis: Chemoselective Synthesis of Sulfoxides from Sulfides
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2022-06-03 , DOI: 10.1002/adsc.202200351
Taiga Mizushima ₁ , Marina Oka ₁ , Yasushi Imada ₂ , Hiroki Iida ₁

Affiliation

The chemoselective electrochemical oxygenation of sulfides to sulfoxides is performed using a biomimetic flavin catalyst that enables the activation of molecular oxygen under a low cathode potential. Diverse functional groups, including alcohols, ketones, aldehydes, cyclopropane, carboxylic acids, pyridine, alkenes, and alkynes, are well tolerated under low-voltage electrolytic conditions.

中文翻译：