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Mechanistic Aspects of the Asymmetric Transfer Hydrogenation in the Manufacture of Noradrenaline
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-05-31 , DOI: 10.1002/ejoc.202200490 Francesco Scorzelli 1 , Daniele Padula 2 , Giusy Tassone 3 , Matteo Zacche 4
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-05-31 , DOI: 10.1002/ejoc.202200490 Francesco Scorzelli 1 , Daniele Padula 2 , Giusy Tassone 3 , Matteo Zacche 4
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The only stereoselective process for the manufacture of noradrenaline known in the literature, an asymmetric transfer hydrogenation, was studied through a catalyst screening and expanded to hydrogenation conditions. The transition states geometries, when using the most stereoselective catalyst, are then evaluated through a computational study.
中文翻译：
去甲肾上腺素生产中不对称转移氢化的机理方面
通过催化剂筛选研究了文献中已知的用于制造去甲肾上腺素的唯一立体选择性方法，即不对称转移氢化，并将其扩展到氢化条件。然后通过计算研究评估过渡态几何形状，当使用最具立体选择性的催化剂时。
更新日期：2022-05-31
中文翻译：
去甲肾上腺素生产中不对称转移氢化的机理方面
通过催化剂筛选研究了文献中已知的用于制造去甲肾上腺素的唯一立体选择性方法，即不对称转移氢化，并将其扩展到氢化条件。然后通过计算研究评估过渡态几何形状，当使用最具立体选择性的催化剂时。
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