Aerobic Baeyer-Villiger Oxidation Catalyzed by Metal Corroles,European Journal of Organic Chemistry

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Aerobic Baeyer-Villiger Oxidation Catalyzed by Metal Corroles
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-05-31 , DOI: 10.1002/ejoc.202200462
Meng-Ni Li ₁ , Bei Wan ₁ , Shuang Yang ₁ , Yan Tang ₁ , Hao Zhang ₁ , Si-Quan Zhang ₁ , Hai-Yang Liu ₂ , Yong Ye ₁

Affiliation

The conversion of cyclohexanone to ϵ-caprolactone had been achieved by metal corrole catalyzed B−V oxidation reaction. It was found that iron corrole Fe(tpfc)Cl exhibited the best catalytic activity for B−V oxidation and the activity could be further enhanced by 4 A-MS additive.

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