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Biocomposites from recycled resources as candidates for laboratory reference material to validate analytical tools used in organic compounds emissions investigation
Building and Environment ( IF 7.1 ) Pub Date : 2022-06-03 , DOI: 10.1016/j.buildenv.2022.109259
Mariusz Marć , Małgorzata Rutkowska , Aleksander Hejna , Mateusz Barczewski

A suitably chosen reference material should meet specific criteria like representing one of the compound classes most commonly occurring in indoor materials as well as having optimal long-term stability during storage and transport to its destination point and having a compact size. The described interdisciplinary pilot research was aimed to develop and characterize a polymer-based candidate for the laboratory reference material (LRM) of selected representatives of monoaromatic hydrocarbons (toluene and furfural) and terpenes emissions. Recycled, petroleum-based low-density polyethylene (LDPE) was applied as a matrix and was filled with plant-based wastes, such as apple pomace (AP), sunflower husks (SH), or yerba mate (YM) residues. The performance and suitability of the developed candidate for use as laboratory reference material was analyzed using FT-IR spectroscopy and differential scanning calorimetry (DSC). The migration potential of the representatives of monoaromatic hydrocarbons and terpenes emitted from the developed polymer material was assessed using the stationary emission microchamber system (μ-CTE 250). In the case of candidates for LRM with the addition of YM and AP, a clear relationship was observed between the samples seasoning time in the chamber and the total amount of VOCs released into the gaseous phase, including identified and determined representatives of terpenes. Furthermore, the existence of a clear relationship between the size (intensity) of the emission defined by the calculated summary parameters (TVOCs and sum of terpenes) and the seasoning/conditioning temperature of polymeric materials with bioadditives was observed.



中文翻译:

来自回收资源的生物复合材料作为实验室参考材料的候选者,以验证用于有机化合物排放调查的分析工具

A suitably chosen reference material should meet specific criteria like representing one of the compound classes most commonly occurring in indoor materials as well as having optimal long-term stability during storage and transport to its destination point and having a compact size. 所描述的跨学科试点研究旨在开发和表征一种基于聚合物的候选物,用于实验室参考材料 (LRM) 的选定代表单芳烃(甲苯和糠醛)和萜烯排放物。回收的石油基低密度聚乙烯 (LDPE) 被用作基质,并填充了植物性废物,例如苹果渣 (AP)、向日葵壳 (SH) 或马黛茶 (YM) 残留物。使用 FT-IR 光谱法和差示扫描量热法 (DSC) 分析了开发的候选物质用作实验室参考物质的性能和适用性。使用固定发射微室系统 (μ-CTE 250) 评估从开发的聚合物材料中释放的单芳烃和萜烯代表的迁移潜力。在添加 YM 和 AP 的 LRM 候选物的情况下,观察到样品在腔室中的老化时间与释放到气相中的 VOC 总量之间存在明显的关系,包括已识别和确定的萜烯代表。此外,

更新日期:2022-06-06
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