当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Straightforward Access to Multifunctional π-Conjugated P-Heterocycles Featuring an Internal Ylidic Bond**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-03 , DOI: 10.1002/anie.202205548
Thomas Delouche 1 , Elsa Caytan 1 , Marie Cordier 1 , Thierry Roisnel 1 , Grégory Taupier 1 , Yann Molard 1 , Nicolas Vanthuyne 2 , Boris Le Guennic 1 , Muriel Hissler 1 , Denis Jacquemin 3 , Pierre-Antoine Bouit 1
Affiliation  

A simple synthesis of P-heterocycles featuring an internal ylidic bond is reported. The stability of the compounds tolerates post-functionalization (direct arylation) and the strategy is also compatible with the preparation of polyaromatic scaffolds (acenes, helicenes). Molecular engineering allows tuning the optical and redox properties, making them valuable dyes for a large panel of photonic or opto-electronic applications.

中文翻译:


直接获得具有内部Ylidic 键的多功能π-共轭P-杂环**



报道了具有内部叶立德键的 P-杂环的简单合成。化合物的稳定性能够耐受后官能化(直接芳基化),并且该策略也与聚芳族支架(并苯、螺烯)的制备相容。分子工程可以调整光学和氧化还原特性,使它们成为大量光子或光电应用的有价值的染料。
更新日期:2022-06-03
down
wechat
bug