Bioinspired and Ligand-Regulated Unnatural Prenylation and Geranylation of Oxindoles with Isoprene under Pd Catalysis,Angewandte Chemie International Edition

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Bioinspired and Ligand-Regulated Unnatural Prenylation and Geranylation of Oxindoles with Isoprene under Pd Catalysis
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-01 , DOI: 10.1002/anie.202207202
Chao-Yang Zhao _{1,

2} , Ying-Ying Liu _{1,

2} , Xiang-Xin Zhang _{1,

2} , Gu-Cheng He _{1,

2} , Heng Liu _{1,

2} , Ding-Wei Ji ₁ , Yan-Cheng Hu ₁ , Qing-An Chen _{1,

2}

Affiliation

A practical strategy has been developed for the bioinspired and ligand-regulated chemoselective unnatural prenylation and geranylation of oxindoles with isoprene under Pd catalysis. The selectivity was governed by modulating the coordination geometry of the Pd catalyst.

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