Donor–acceptor alternating conjugated polymers with various electronic characteristics, including strong donor–strong acceptor, are synthesized via living Suzuki–Miyaura catalyst-transfer polymerization in a controlled manner. The polymerization also works with a complex quateraryl monomer and allows for one-pot di(tri)block copolymer synthesis. The resulting polymers have tunable optical and electrochemical properties based on the combination of building units.

中文翻译：

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Living Suzuki-Miyaura催化剂-转移聚合精密合成各种低带隙供体-受体交替共轭聚合物

通过活性 Suzuki-Miyaura 催化剂转移聚合以受控方式合成了具有各种电子特性的供体-受体交替共轭聚合物，包括强供体-强受体。该聚合还适用于复杂的季芳基单体，并允许一锅二（三）嵌段共聚物合成。基于构建单元的组合，所得聚合物具有可调节的光学和电化学特性。