Alkyl/Glycosyl Sulfoxides as Radical Precursors and Their Use in the Synthesis of Pyridine Derivatives**,Angewandte Chemie International Edition

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Alkyl/Glycosyl Sulfoxides as Radical Precursors and Their Use in the Synthesis of Pyridine Derivatives**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-05-31 , DOI: 10.1002/anie.202204922
Demeng Xie ₁ , Yingwei Wang ₁ , Xia Zhang ₁ , Zhengyan Fu ₁ , Dawen Niu ₁

Affiliation

Simple and readily available alkyl sulfoxides are shown to be suitable precursors to radicals. Alkyl sulfoxides, N-methoxy pyridinium salts and fluoride anions form electron donor–acceptor (EDA) complexes, which, upon visible-light irradiation, undergo a radical chain process to give various pyridine derivatives.

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