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Intramolecular Energy and Solvent-Dependent Chirality Transfer within a BINOL-Perylene Hetero-Cyclophane
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-05-31 , DOI: 10.1002/anie.202206706
Guanghui Ouyang 1, 2 , Jessica Rühe 1 , Yang Zhang 3 , Mei-Jin Lin 3 , Minghua Liu 2 , Frank Würthner 1
Affiliation  

A chiral perylene bisimide (PBI) hetero-cyclophane comprising a chiral binaphthol bisimide (BBI) dye and a dynamically racemic PBI dye shows quantitative energy and solvent-dependent chirality transfer among its components, thereby leading to an amplified bright red circularly polarized luminescence from PBI.

中文翻译:


BINOL-苝杂环芳内的分子内能量和溶剂依赖性手性转移



包含手性联萘酚双酰亚胺 (BBI) 染料和动态外消旋 PBI 染料的手性苝双酰亚胺 (PBI) 杂环烷在其组分之间显示出定量能量和溶剂依赖性手性转移,从而导致 PBI 发出放大的亮红色圆偏振发光。
更新日期:2022-05-31
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