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Supported Anionic Gold Nanoparticle Catalysts Modified Using Highly Negatively Charged Multivacant Polyoxometalates
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-05-29 , DOI: 10.1002/anie.202205873
Kang Xia 1 , Takafumi Yatabe 1 , Kentaro Yonesato 1 , Tomohiro Yabe 1 , Soichi Kikkawa 2 , Seiji Yamazoe 2, 3 , Ayako Nakata 3, 4 , Kazuya Yamaguchi 1 , Kosuke Suzuki 1, 3
Affiliation  

A method is reported for the design of supported anionic gold nanoparticle catalysts modified using highly negatively charged multivacant lacunary polyoxometalates. Enhanced catalytic activity and stability of supported anionic gold nanoparticle catalysts was accessed in the aerobic oxidative dehydrogenation of piperidone derivatives to the corresponding enaminones.

中文翻译:

使用高负电荷多空位多金属氧酸盐改性的负载型阴离子金纳米颗粒催化剂

报道了一种设计负载型阴离子金纳米颗粒催化剂的方法,该催化剂使用带高负电荷的多空位空穴多金属氧酸盐进行改性。在哌啶酮衍生物需氧氧化脱氢生成相应烯胺酮的过程中,负载型阴离子金纳米颗粒催化剂的催化活性和稳定性得到了提高。
更新日期:2022-05-29
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