Ruthenium(II)-Catalyzed Hydroamination of Allenoates: A Regioselective Synthesis of Allylamines,Advanced Synthesis & Catalysis

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Ruthenium(II)-Catalyzed Hydroamination of Allenoates: A Regioselective Synthesis of Allylamines
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2022-05-17 , DOI: 10.1002/adsc.202200184
Mingdong Zhou ₁ , Hua Wang ₂ , He Wang ₁ , Lei Li ₁ , Xin Wang ₃ , Ran Sun ₁

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A ruthenium(II)-catalyzed hydroamination of allenoates with arylamines has been developed. This strategy provides an approach to synthesize E-allylic amines in good yields with high atom-economy and high levels of chemo-, regio- and E-selectivities with a broad substrate scope.

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