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Sulfonylation enabled through the photoactivation of EDA complexes
Chem Catalysis Pub Date : 2022-04-21 , DOI: 10.1016/j.checat.2022.03.028
Simon De Kreijger 1 , Ludovic Troian-Gautier 1
Affiliation  

In this issue of Chem Catalysis, Molander and co-workers report the visible-light photoactivation of electron donor-acceptor (EDA) complexes formed between thianthrenium and sodium sulfinate derivatives to generate sulfone-containing compounds in moderate to good yields. This approach can be used for late-stage functionalization and enables the retention of halide handles.



中文翻译:

通过 EDA 复合物的光活化实现磺酰化

在本期Chem Catalysis中,Molander 及其同事报告了在硫蒽和亚磺酸钠衍生物之间形成的电子供体 - 受体 (EDA) 配合物的可见光光活化,以产生中等至高产率的含砜化合物。这种方法可用于后期功能化并能够保留卤化物手柄。

更新日期:2022-04-22
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