In the inaugural issue of Tetrahedron Chem, Liu, Wei, and Shi describe a photoredox catalyzed variant of the Cloke-Wilson rearrangement featuring the ring-opening and interrupted recyclization of cyclopropyl ketones by intramolecular nucleophilic attack with an indole moiety, thus leading to unique macrocyclic frameworks.

中文翻译：

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克洛克-威尔逊重排的光化学中断

在Tetrahedron Chem的创刊号中，Liu、Wei 和 Shi 描述了一种光氧化还原催化的 Cloke-Wilson 重排变体，其特征是环丙基酮通过吲哚部分的分子内亲核攻击开环和间断再循环，从而产生独特的大环构架。