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Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
International Journal of Chemical Engineering ( IF 2.3 ) Pub Date : 2022-04-20 , DOI: 10.1155/2022/5006911
Perumal Asaithambi 1 , Mamuye Busier Yesuf 1 , Seifu Kebede Debela 1 , Rajendran Govindarajan 2 , N. M. Hariharan 3 , Esayas Alemayehu 1, 4
Affiliation  

Ozonation is one of the most effective and efficient advanced oxidation processes (AOPs) and has shown great potential in the treatment of industrial effluent and wastewater. In the present work, the ozone-Fenton process for % COD and color removal together with electrical energy per order (EE/O) determination for distillery industrial wastewater (DIW) was established. The process was developed by combining the ozone (O3) with the Fenton (Fe2+/H2O2) process. The ozone-Fenton (O3/Fe2+/H2O2) was compared with other treatment processes such as O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 for EE/O together with % COD and color removal efficiency for DIW. The removal of color at 100% and chemical oxygen demand (COD) of 96.875% were achieved with a minimum of EE/O of 0.5315 kWh/m3 using the O3/Fe2+/H2O2 process by operating at optimum conditions. The % COD and color values obtained using O3/Fe2+/H2O2 were significantly higher than those obtained using O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 processes. The % color, % COD removal, and its associated EE/O were evaluated by varying Fe2+, H2O2, O3 inlet and COD concentration, and initial wastewater pH using the O3/Fe2+/H2O2 process. The synergy effect of the O3 and Fe2+/H2O2 processes was evaluated and reported. Our experimental findings suggest that combining O3 with the Fe2+/H2O2 process could effectively treat industrial effluent and wastewater.

中文翻译:

使用臭氧辅助 Fenton 工艺处理酿酒厂工业废水:每个订单评估用电能去除颜色和化学需氧量

臭氧化是最有效和最高效的高级氧化工艺(AOPs)之一,在处理工业废水和废水方面显示出巨大的潜力。在目前的工作中,建立了用于测定蒸馏工业废水 (DIW) 的 % COD 和颜色去除以及单次电能 (EE/O) 测定的臭氧-芬顿工艺。该工艺是通过将臭氧 (O 3 ) 与芬顿 (Fe 2+ /H 2 O 2 ) 工艺相结合而开发的。臭氧-芬顿(O 3 /Fe 2+ /H 2 O 2)与其他处理工艺如O 3、Fe 2+、H 2 O进行比较2、O 3 /Fe 2+、O 3 /H 2 O 2和Fe 2+ /H 2 O 2用于EE/O以及%COD和DIW的颜色去除效率。使用 O 3 /Fe 2+ /H 2 O 2工艺,在最佳运行条件下,以 0.5315 kWh/m 3的最低 EE/O 实现了 100% 的颜色去除和 96.875% 的化学需氧量 (COD)条件。使用 O 3 /Fe 2+ /H 2 O 2获得的 % COD 和颜色值显着高于使用O 3、Fe 2+、H 2 O 2、O 3 /Fe 2+、O 3 /H 2 O 2和Fe 2+ /H 2 O 2工艺获得的那些。通过改变 Fe 2+、H 2 O 2、O 3入口和 COD 浓度以及使用 O 3 /Fe 2+ /H 2 O的初始废水 pH 值来评估 % 颜色、% COD 去除率及其相关的 EE/ O 2过程。O的协同效应对3和 Fe 2+ /H 2 O 2过程进行了评估和报告。我们的实验结果表明,将O 3与Fe 2+ /H 2 O 2工艺相结合可以有效地处理工业废水和废水。
更新日期:2022-04-20
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