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Characteristics of the chemical composition and source apportionment of PM2.5 for a one-year period in Wuhan, China
Journal of Atmospheric Chemistry ( IF 3.0 ) Pub Date : 2022-03-31 , DOI: 10.1007/s10874-022-09431-6
Xiaoyu Zhang 1 , Guixiang Ji 1 , Lingya Kong 1 , Xin Zhao 1 , Rongrong Ying 1 , Xiaowu Peng 2 , Wenjun Yin 3 , Tian Xu 3 , Juan Cheng 3 , Lin Wang 3
Affiliation  

In this study, 123 PM2.5 filter samples were collected in Wuhan, Hubei province from December 2014 to November 2015. Water- soluble inorganic ions (WSIIs), elemental carbon (EC), organic carbon (OC) and inorganic elements were measured. Source apportionment and back trajectory was investigated by the positive matrix factorization (PMF) model and the hybrid single particle lagrangian integrated trajectory (HYSPLIT) model, respectively. The annual PM2.5 concentration was 80.5 ± 38.2 μg/m3, with higher PM2.5 in winter and lower in summer. WSIIs, OC, EC, as well as elements contributed 46.8%, 14.8%, 6.7% and 8% to PM2.5 mass concentration, respectively. SO42−, NO3 and NH4+ were the dominant components, accounting for 40.2% of PM2.5 concentrations. S, K, Cl, Ba, Fe, Ca and I were the main inorganic elements, and accounted for 65.2% of the elemental composition. The ratio of NO3/SO42− was 0.86 ± 0.72, indicating that stationary sources play dominant role on PM2.5 concentration. The ratio of OC/EC was 2.9 ± 1.4, suggesting the existence of secondary organic carbon (SOC). Five sources were identified using PMF model, which included secondary inorganic aerosols (SIA), coal combustion, industry, vehicle emission, fugitive dust. SIA, coal combustion, as well as industry were the dominant contributors to PM2.5 pollution, accounting for 34.7%, 20.5%, 19.6%, respectively.



中文翻译:

武汉市一年来PM2.5化学成分及来源解析特征

本研究于2014年12月至2015年11月在湖北省武汉市采集了123个PM 2.5过滤器样品,测量了水溶性无机离子(WSII)、元素碳(EC)、有机碳(OC)和无机元素。分别通过正矩阵分解(PMF)模型和混合单粒子拉格朗日积分轨迹(HYSPLIT)模型研究源解析和反向轨迹。 PM 2.5年浓度为80.5±38.2 μg/m 3 ,PM 2.5冬季较高,夏季较低。 WSIIs、OC、EC以及元素对PM 2.5质量浓度的贡献率分别为46.8%、14.8%、6.7%和8%。 SO 4 2−、NO 3 和NH 4 +是主要成分,占PM 2.5浓度的40.2%。 S、K、Cl、Ba、Fe、Ca、I 为主要无机元素,占元素组成的 65.2%。 NO 3 /SO 4 2−比值为0.86 ± 0.72,表明固定污染源对PM 2.5浓度起主导作用。 OC/EC比值为2.9±1.4,表明存在次生有机碳(SOC)。使用PMF模型确定了五个来源,其中包括二次无机气溶胶(SIA)、煤炭燃烧、工业、车辆排放、扬尘。空气污染、燃煤和工业是 PM 2.5污染的主要贡献者,分别占 34.7%、20.5%、19.6%。

更新日期:2022-03-31
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