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Phase engineering in NaNbO3 antiferroelectrics for high energy storage density
Journal of Materiomics ( IF 9.4 ) Pub Date : 2022-03-29 , DOI: 10.1016/j.jmat.2022.03.004
Zhengu Chen 1, 2 , Shuaifei Mao 2 , Li Ma 2 , Gengguang Luo 2 , Qin Feng 2 , Zhenyong Cen 2 , Fujita Toyohisa 2 , Xiuning Peng 3 , Laijun Liu 4 , Huanfu Zhou 4 , Changzheng Hu 4 , Nengneng Luo 2, 5
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The NaNbO3 antiferroelectrics have been considered as a potential candidate for dielectric capacitors applications. However, the high-electric-field-unstable antiferroelectric phase resulted in low energy storage density and efficiency. Herein, good energy storage properties were realized in (1-x)NaNbO3-xNaTaO3 ceramics, by building a new phase boundary. As a result, a high recoverable energy density (Wrec) of 2.2 J/cm3 and efficiency (η) of 80.1% were achieved in 0.50NaNbO3-0.50NaTaO3 ceramic at 300 kV/cm. The excellent energy storage performance originates from an antiferroelectric-paraelectric phase boundary with simultaneously high polarization and low hysteresis, by tailoring the ratio of antiferroelectric and paraelectric phases. Moreover, the 0.50NaNbO3-0.50NaTaO3 ceramic also exhibited good temperature and frequency stability, together with excellent charge-discharge performance. The results pave a good way of designing new NaNbO3-based antiferroelectrics with good energy storage performance.



中文翻译:

用于高能量存储密度的 NaNbO3 反铁电体中的相工程

NaNbO 3反铁电体已被认为是电介质电容器应用的潜在候选者。然而,高电场不稳定的反铁电相导致低能量存储密度和效率。在此,通过建立新的相界,(1- x )NaNbO 3 - x NaTaO 3陶瓷实现了良好的储能性能。结果,在 0.50NaNbO 3 -0.50NaTaO 3中实现了 2.2 J/cm 3的高可恢复能量密度 ( W rec ) 和80.1% 的效率 ( η )陶瓷在 300 kV/cm。通过调整反铁电相和顺电相的比例,优异的储能性能源于同时具有高极化和低滞后的反铁电-顺电相界。此外,0.50NaNbO 3 -0.50NaTaO 3陶瓷还表现出良好的温度和频率稳定性,以及优异的充放电性能。该结果为设计具有良好储能性能的新型 NaNbO 3基反铁电体铺平了道路。

更新日期:2022-03-29
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