The presence of recalcitrant contaminants in wastewater is major challenge to decrease pollution and associated health issues. As a consequence, membrane technologies have recently attracted industrial attention, yet a major setback of membrane employment is membrane fouling which leads to frequent discarding of membrane modules. More than 45% of all membrane fouling cases are caused by biofilms that are resistant to antimicrobial agents. Here we review polymeric membranes with antifouling properties, with focus on surface properties, fabrication, characterization, biocatalysis using enzymes and application towards the removal of dyes, phenol, pesticides and fertilizers. Nano-engineered fabrication of polymeric membranes allow to decrease fouling by 80–90%. Immobilized oxidoreductases in polymeric membranes allow 65–98% removal contaminants in wastewater.

废水中存在顽固性污染物是减少污染和相关健康问题的主要挑战。因此，膜技术最近引起了工业界的关注，但膜应用的一个主要挫折是膜污染，这导致膜组件的频繁丢弃。超过 45% 的膜污染案例是由对抗菌剂有抗药性的生物膜引起的。在这里，我们回顾了具有防污性能的聚合物膜，重点关注表面性能、制造、表征、使用酶的生物催化以及在去除染料、苯酚、杀虫剂和肥料方面的应用。聚合物膜的纳米工程制造可以将污垢减少 80-90%。