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Examination of Milstein Ru-PNN and Rh-Tribi/Tetrabi dual metal catalyst for isomerization-linear-hydroformylation of C4 raffinate and internal olefins
Green Synthesis and Catalysis ( IF 8.2 ) Pub Date : 2022-2-1 , DOI: 10.1016/j.gresc.2021.10.010
Runtong Zhang , Xin Yan , Shao-Tao Bai , Caiyou Chen , Bozhao Nan , Baode Ma , Jialin Wen , Xumu Zhang

A dual metal catalysis system combining a Milstein Ru-PNN catalyst and a Rh-catalyst based on multidentate phosphorus ligand was disclosed for isomerization-linear-hydroformylation of C4 raffinate (mixed butenes) and internal olefins with significantly improved selectivities and activities.

中文翻译:

Milstein Ru-PNN 和 Rh-Tribi/Tetrabi 双金属催化剂对 C4 萃余液和内烯烃的异构化线性加氢甲酰化的研究

公开了一种结合 Milstein Ru-PNN 催化剂和基于多齿磷配体的 Rh 催化剂的双金属催化系统,用于 C4 萃余液(混合丁烯)和内烯烃的异构化-线性加氢甲酰化,具有显着提高的选择性和活性。
更新日期:2022-03-28
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