Alternating current electrolysis (ACE) is an emerging powerful synthetic tool, which principally resembles photoredox catalysis strategies. Its periodically alternating polarity feature allows oxidation and reduction processes to take place on the same electrode surface in a well-controlled manner via the fine-tuning of current frequency along with other reaction parameters. Therefore, many challenging transformations in typical direct electrolysis, including constant current electrolysis or constant potential electrolysis, could be achieved via ACE. The recent advances in the organic synthesis using this emerging technology and its advantages over direct electrolysis are highlighted.

中文翻译：

---

交流电电解：光氧化还原催化模拟和超越

交流电电解 (ACE) 是一种新兴的强大合成工具，主要类似于光氧化还原催化策略。其周期性交替极性特性允许通过微调电流频率和其他反应参数，以良好控制的方式在同一电极表面上发生氧化和还原过程。因此，可以通过 ACE 实现典型直接电解中的许多具有挑战性的转变，包括恒流电解或恒电位电解。强调了使用这种新兴技术进行有机合成的最新进展及其相对于直接电解的优势。