当前位置: X-MOL 学术Org. Biomol. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
H–F bond insertions into α-diazo carbonyl compounds
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2022-03-24 , DOI: 10.1039/d2ob00400c
Laiéli S Munaretto 1 , Rafael D C Gallo 1 , Luiz Paulo M O Leão 1 , Igor D Jurberg 1
Affiliation  

A reaction for H–F bond insertion into α-diazo carbonyl compounds is reported. The protocol describes a simple reaction setup employing commercially available HF·pyr (Olah reagent) as the fluorine source. The method is rapid and practical, and allows access to a broad range of α-fluorinated carbonyl compounds in generally good yields.

中文翻译:

H-F 键插入 α-重氮羰基化合物

报道了将 H-F 键插入 α-重氮羰基化合物的反应。该协议描述了一个简单的反应设置,使用市售的 HF·pyr(Olah 试剂)作为氟源。该方法快速实用,并且可以以通常良好的收率获得广泛的 α-氟化羰基化合物。
更新日期:2022-03-24
down
wechat
bug