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H–F bond insertions into α-diazo carbonyl compounds
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2022-03-24 , DOI: 10.1039/d2ob00400c Laiéli S Munaretto 1 , Rafael D C Gallo 1 , Luiz Paulo M O Leão 1 , Igor D Jurberg 1
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2022-03-24 , DOI: 10.1039/d2ob00400c Laiéli S Munaretto 1 , Rafael D C Gallo 1 , Luiz Paulo M O Leão 1 , Igor D Jurberg 1
Affiliation
A reaction for H–F bond insertion into α-diazo carbonyl compounds is reported. The protocol describes a simple reaction setup employing commercially available HF·pyr (Olah reagent) as the fluorine source. The method is rapid and practical, and allows access to a broad range of α-fluorinated carbonyl compounds in generally good yields.
中文翻译:
H-F 键插入 α-重氮羰基化合物
报道了将 H-F 键插入 α-重氮羰基化合物的反应。该协议描述了一个简单的反应设置,使用市售的 HF·pyr(Olah 试剂)作为氟源。该方法快速实用,并且可以以通常良好的收率获得广泛的 α-氟化羰基化合物。
更新日期:2022-03-24
中文翻译:
H-F 键插入 α-重氮羰基化合物
报道了将 H-F 键插入 α-重氮羰基化合物的反应。该协议描述了一个简单的反应设置,使用市售的 HF·pyr(Olah 试剂)作为氟源。该方法快速实用,并且可以以通常良好的收率获得广泛的 α-氟化羰基化合物。