The possibility of photocatalytic C(sp³)–H activation of aliphatic amines with the participation of decatungstate anion and their subsequent interaction with an acrylic acid ester has been demonstrated. Irradiation of reaction mixtures containing an aliphatic amine in the form of trifluoroacetic acid salt, acrylic acid tert-butyl ester, and sodium decatungstate Na₄W₁₀O₃₂ or tetra-n-butylammonium has been shown to result in the formation of branched-chain amino acid esters.

中文翻译：

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十钨酸阴离子光催化C(sp3)-H活化脂肪胺获得氨基酸

已经证明了在十钨酸阴离子的参与下光催化 C( sp ³ )-H 活化脂肪胺的可能性以及它们随后与丙烯酸酯的相互作用。辐照含有呈三氟乙酸盐、丙烯酸叔丁酯和十钨酸钠 Na ₄ W ₁₀ O ₃₂或四正丁基铵形式的脂肪胺的反应混合物已显示导致支链的形成氨基酸酯。