Solvothermal syntheses, characterizations and photocatalytic properties of two copper-rich thiostannates,Inorganic Chemistry Communications

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Solvothermal syntheses, characterizations and photocatalytic properties of two copper-rich thiostannates
Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2022-02-18 , DOI: 10.1016/j.inoche.2022.109323
Yanhua Li ₁ , Xiaoyu Cao ₁ , Min Ji ₁ , Zhonglu You ₂ , Yonglin An ₁

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Two copper-rich thiostannates RbCuSnS () and (HO)RbCuSnS () were synthesized solvothermally. Compound possesses a three-dimensional structure containing [CuS] icosahedral clusters. Compound displays a dual-channel structure and the Cu/Sn molar ratio of this compound is the highest in the known three-dimensional open-framework sulfides. The optical properties and photocatalytic degradation performances for methylene blue of and were also studied.

中文翻译：

两种富铜硫锡酸盐的溶剂热合成、表征及光催化性能

采用溶剂热法合成了两种富铜硫锡酸盐 RbCuSnS () 和 (HO)RbCuSnS ()。化合物具有包含[CuS]二十面体簇的三维结构。化合物呈现双通道结构，且该化合物的Cu/Sn摩尔比是已知的三维开放骨架硫化物中最高的。还研究了亚甲基蓝的光学性质和光催化降解性能。

更新日期：2022-02-18

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