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Protective Cr coatings with CrN/Cr multilayers for zirconium fuel claddings
Surface & Coatings Technology ( IF 5.4 ) Pub Date : 2022-01-20 , DOI: 10.1016/j.surfcoat.2022.128131
D.V. Sidelev 1, 1 , S.E. Ruchkin 1 , M.S. Syrtanov 1 , E.B. Kashkarov 1 , I.A. Shelepov 2 , A.G. Malgin 2 , K.K. Polunin 3 , K.V. Stoykov 3 , A.A. Mokrushin 3
Affiliation  

Cr coatings with CrN/Cr multilayers with a layer thickness of 100, 250 and 750 nm were deposited by a multi-cathode magnetron sputtering on E110 zirconium alloy in Ar and Ar + N2 atmosphere. The mechanical properties of the as-deposited coatings were measured by scratch testing and tribometry. A comparative study of crack and oxidation resistance of the Cr-coated E110 alloy was performed under thermal cycling (1000 °С) and high-temperature (1200–1400 °С) steam oxidation conditions. The influence of the CrN/Cr multilayers and their thickness on the mechanical properties and oxidation resistance of the coated E110 alloy is discussed. It is found that the CrN/Cr multilayers can limit interdiffusion between the coating and E110 alloy at high temperatures only for a short period.



中文翻译:

用于锆燃料包壳的 CrN/Cr 多层保护性 Cr 涂层

在 Ar 和 Ar + N 2气氛中,通过多阴极磁控管溅射在 E110 锆合金上沉积具有层厚为 100、250 和 750 nm 的 CrN/Cr 多层的 Cr 涂层。通过划痕测试和摩擦测量法测量沉积涂层的机械性能。在热循环(1000°С)和高温(1200-1400°С)蒸汽氧化条件下,对镀铬的 E110 合金的抗裂纹和抗氧化性进行了比较研究。讨论了CrN/Cr多层及其厚度对涂层E110合金的机械性能和抗氧化性的影响。研究发现,CrN/Cr 多层膜在高温下只能在短时间内限制涂层和 E110 合金之间的相互扩散。

更新日期:2022-01-23
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