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Synthesis of BiVO4/g-C3N4 S-scheme heterojunction via a rapid and green microwave route for efficient removal of glyphosate
Separation and Purification Technology ( IF 8.1 ) Pub Date : 2022-01-17 , DOI: 10.1016/j.seppur.2022.120507
Zengyue Chen 1, 2 , Yunfeng Li 2 , Fei Tian 2 , Xin Chen 1 , Zhansheng Wu 1, 2
Affiliation  

In this work, a green reaction route for the preparation of BiVO4/g-C3N4 composite is constructed using the acetic acid and reusable ethylene glycol system combined with the microwave method. The rice grain-like BiVO4 is successfully deposited on the surface of hollow tubular g-C3N4 to form a S-scheme heterojunction within 25 min. The performance of the prepared photocatalysts is evaluated by removing glyphosate, methyl orange and tetracycline hydrochloride from simulated agricultural and urban runoff. The degradation evaluation results show that acetic acid in this route could play a better induction role compared to the conventional inducer nitric acid, while the ethylene glycol in this route can be recycled. The recovery of ethylene glycol could reach more than 85%, and the performance of the produced photocatalyst will not be decreased after the recovery of ethylene glycol reaches 20 times. The BV/CN60-R20 sample has the highest photocatalytic activity for glyphosate removal under simulated sunlight irradiation, which is 14.5 times and 9.7 times higher than that of pure BiVO4 and g-C3N4, respectively. In summary, the establishment of the ethylene glycol and acetic acid system not only provides a new perspective for the replacement of strong acids in the preparation of BiVO4-based photocatalyst but also provides a reference for the construction of other harmless and recyclable systems.



中文翻译:

快速绿色微波路线合成BiVO4/g-C3N4 S型异质结高效去除草甘膦

本工作以醋酸和可重复使用的乙二醇体系结合微波法构建了制备BiVO 4 /gC 3 N 4复合材料的绿色反应路线。米粒状BiVO 4成功沉积在中空管状gC 3 N 4表面,在25 min内形成S型异质结。通过去除草甘膦、甲基橙和四环素来评价制备的光催化剂的性能 模拟农业和城市径流中的盐酸盐。降解评价结果表明,与传统的诱导剂硝酸相比,该路线中的乙酸可以发挥更好的诱导作用,而该路线中的乙二醇可以回收利用。乙二醇回收率可达85%以上,生产的光催化剂在乙二醇回收率达到20倍后性能不会下降。BV/CN 60 -R 20样品在模拟太阳光照射下对草甘膦去除的光催化活性最高,分别是纯BiVO 4和gC 3 N 4的14.5倍和9.7倍, 分别。综上所述,乙二醇和乙酸体系的建立不仅为强酸替代制备BiVO 4基光催化剂提供了新的视角,也为其他无害、可回收体系的构建提供了参考。

更新日期:2022-01-23
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