当前位置: X-MOL 学术Prog. Quant. Electron. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Advances in single crystals and thin films of chiral hybrid metal halides
Progress in Quantum Electronics ( IF 7.4 ) Pub Date : 2022-01-11 , DOI: 10.1016/j.pquantelec.2022.100375
Zhihang Guo 1 , Junzi Li 1 , Rui Chen 2 , Tingchao He 1
Affiliation  

Chiral organic–inorganic hybrid metal halides (HMHs), as an emerging class of chiral semiconductor materials, have attracted unparalleled interest from multi-purpose perspectives, as a result of their easily accessible solution-grown methods, plentiful chemical structure and composition, as well as unique and exciting optoelectronic properties. Recently, substantial progress has been made in the synthesis of chiral HMHs, spectroscopic characterization and fabrication of optoelectronic devices. Although several reviews about the chiroptical properties and applications of chiral HMHs have been published, the comprehensive summary of the basic structural frameworks, fundamental physics and strategies for the modulation of optical activity, which are vital for the design of chiral HMHs and development of relevant optoelectronic applications, are still insufficient. In this review, we summarize the research progress from fundamentals to applications for the single crystals and thin films of chiral HMHs that are conducive to the development of practical optoelectronic devices. First, diverse structural frameworks and synthetic methods of chiral HMHs are systematically summarized. Afterward, fundamental physics and strategies for the modulation of optical activity as well as their related optoelectronic applications are comprehensively reviewed. Finally, we put forward the current challenges in this rapidly evolving field and present an outlook on future prospects to further develop chiral HMHs for various applications.



中文翻译:

手性杂化金属卤化物的单晶和薄膜研究进展

手性有机-无机杂化金属卤化物(HMHs)作为一类新兴的手性半导体材料,由于其易于获得的溶液生长方法、丰富的化学结构和组成,从多用途的角度引起了无与伦比的兴趣。作为独特而令人兴奋的光电特性。最近,在手性 HMH 的合成、光谱表征和光电器件的制造方面取得了实质性进展。尽管已经发表了几篇关于手性 HMH 的手性光学特性和应用的评论,但对基本结构框架、基础物理和光学活性调制策略的全面总结对于手性 HMH 的设计和相关光电应用的开发至关重要,但仍然不足。在这篇综述中,我们总结了手性HMHs单晶和薄膜从基础到应用的研究进展,有利于实用光电器件的发展。首先,系统总结了手性HMHs的多种结构框架和合成方法。随后,对光学活性调制的基础物理和策略及其相关的光电应用进行了全面综述。最后,我们提出了这一快速发展领域当前面临的挑战,并对未来前景进行展望,以进一步开发用于各种应用的手性 HMH。

更新日期:2022-01-11
down
wechat
bug