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Influence of the sorption pressure and K2CO3 loading of a MgO-based sorbent for application to the SEWGS process
Korean Journal of Chemical Engineering ( IF 2.9 ) Pub Date : 2022-01-11 , DOI: 10.1007/s11814-021-0967-1
Do Yeong Ryu 1, 2 , Tae-Young Kim 1 , Soo Yeong In 1 , Jae Chang Kim 1 , Jae Kuk Kim 2 , Jae Eun Hwang 2 , Seongbin Jo 3 , Soo Chool Lee 4
Affiliation  

MgO-based sorbents were prepared by impregnation with K2CO3 at different loadings. This study examined the CO2 absorption and regeneration properties of MgO-based sorbents at various pressures. The CO2 capture capacity of the PMI-30 sorbent increased to 204.4 mg CO2/g sorbent with increasing absorption pressure through CO2 absorption by MgO itself and K2CO3 by generating structures, such as MgCO3·3H2O and K2Mg(CO3)2. However, no KHCO3 phase was observed after CO2 absorption at 1, 10, and 20 atm. The CO2 capture capacity of the MgO and PMI-10, 20, 30, and 40 sorbents was the 94.6, 129.9, 156.6, 204.4, and 239.4 mg CO2/g sorbent, respectively. The CO2 capture capacity of MgO in the PMI sorbent was relatively constant regardless of the decreasing MgO content and increasing K2CO3 content. The CO2 absorption ability of MgO was calculated by substracting theoretical CO2 capture capacity of K2CO3 from the total capacity of sorbents. The TPD experiment performed at 1 atm after CO2 absorption at 20 atm showed that the regeneration temperature of the PMI sorbents differed according to the K2CO3 loading.



中文翻译:

用于 SEWGS 工艺的 MgO 基吸附剂的吸附压力和 K2CO3 负载量的影响

MgO 基吸附剂是通过在不同负载量下用 K 2 CO 3浸渍来制备的。本研究考察了MgO 基吸附剂在不同压力下的 CO 2吸收和再生性能。PMI-30吸附剂的CO 2捕获能力随着吸收压力的增加而增加至204.4 mg CO 2 /g 吸附剂,通过MgO本身吸收CO 2和通过生成MgCO 3 ·3H 2 O和K等结构的K 2 CO 3 2 Mg(CO 3 ) 2。然而,在CO 2之后没有观察到KHCO 3在 1、10 和 20 个大气压下的吸收。MgO 和 PMI-10、20、30 和 40 吸附剂的 CO 2捕获能力分别为 94.6、129.9、156.6、204.4 和 239.4 mg CO 2 /g 吸附剂。无论降低 MgO 含量和增加 K 2 CO 3含量,PMI 吸附剂中 MgO的 CO 2捕获能力相对恒定。通过从吸附剂的总容量中减去K 2 CO 3 的理论CO 2捕获容量来计算MgO的CO 2吸附容量。TPD 实验在 CO 2后 1 个大气压下进行在 20 atm 下的吸收表明,PMI 吸附剂的再生温度因 K 2 CO 3负载而异。

更新日期:2022-01-12
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