p–d Orbital Hybridization Induced by a Monodispersed Ga Site on a Pt3Mn Nanocatalyst Boosts Ethanol Electrooxidation,Angewandte Chemie International Edition

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p–d Orbital Hybridization Induced by a Monodispersed Ga Site on a Pt3Mn Nanocatalyst Boosts Ethanol Electrooxidation
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-01-09 , DOI: 10.1002/anie.202115735
Yao Wang ₁ , Meng Zheng ₂ , Yunrui Li ₃ , Chenliang Ye ₂ , Juan Chen ₃ , Jinyu Ye ₄ , Qinghua Zhang ₅ , Jiong Li ₆ , Zhiyou Zhou ₄ , Xian-Zhu Fu ₂ , Jin Wang ₂ , Shi-Gang Sun ₄ , Dingsheng Wang ₁

Affiliation

The monodispersed Ga site tailored Pt₃Mn nanocatalyst based on high-indexed facets was constructed and shows excellent EOR performance with high activity and selectivity towards the C2 reaction pathway, which was attributed to the unconventional p–d orbital hybridization and atomic-level interface synergy.

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