The high photocatalytic activity of environmentally benign Keggin-type polyoxometalate (POM) was introduced into polyethersulfone (PES) membrane to promote membrane anti-fouling and self-cleaning functionality. Neat PES and POM/PES hybrid membranes were synthesized via phase inversion method. X-ray diffraction (XRD) and attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy proved the success of synthesizing Keggin-type POM. The traits of the membranes were evaluated using scanning electron microscopy (SEM), ATR-FTIR, contact angle measurement, porosity and porometer. The hydrophilicity of all the POM/PES hybrid membranes was enhanced and resulted in the reduction of contact angle of the membrane (52.21±0.1101°, 45.11±0.6657° and 50.30±0.1054°) for 0.025, 0.05 and 0.1 wt% POM/PES hybrid membranes, respectively, compared to that of the neat PES membrane (57.30±0.0817°). Additionally, all the POM/PES hybrid membranes showed excellent anti-fouling and self-cleaning characteristics as compared to that of the neat PES membrane. 0.05 wt% POM/PES hybrid membrane outstood all the other membranes, which marks the HA rejection at 77.12% and was able to achieve flux recovery ratio (FRR) of 111.34% with temporal superhydrophilicity effect in just merely 150 seconds at 254 nm UV irradiation.

将环境友好型 Keggin 型多金属氧酸盐 (POM) 的高光催化活性引入聚醚砜 (PES) 膜中，以促进膜的防污和自清洁功能。Neat PES 和 POM/PES 杂化膜通过相转化法合成。X射线衍射（XRD）和衰减全反射-傅里叶变换红外（ATR-FTIR）光谱证明合成Keggin型聚甲醛是成功的。使用扫描电子显微镜 (SEM)、ATR-FTIR、接触角测量、孔隙率和孔隙率计评估膜的特性。所有 POM/PES 杂化膜的亲水性均增强，导致膜的接触角降低（52.21±0.1101°、45.11±0.6657° 和 50.30±0.1054°），分别为 0.025、0.05 和 0.1 wt% POM/PES混合膜，分别，与纯PES膜相比（57.30±0.0817°）。此外，与纯 PES 膜相比，所有 POM/PES 杂化膜都表现出优异的防污和自清洁特性。0.05 wt% POM/PES 杂化膜优于所有其他膜，这标志着 HA 排斥率为 77.12%，在 254 nm 紫外线照射下仅 150 秒即可实现 111.34% 的通量恢复率 (FRR) 和瞬时超亲水性效应.