当前位置: X-MOL 学术Korean J. Chem. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
A RuO2IrO2 electrocatalyst with an optimal composition and novel microstructure for oxygen evolving in the single cell
Korean Journal of Chemical Engineering ( IF 2.9 ) Pub Date : 2022-01-09 , DOI: 10.1007/s11814-021-0942-x
Feng Ye 1 , Yanpeng Cao 1 , Yakun Yang 1 , Yuancheng Feng 1 , Peng Liu 1 , Chao Xu 1 , Xiaoze Du 1 , Weiwei Han 2 , Woochul Yang 2 , Guicheng Liu 2
Affiliation  

A highly active RuO2IrO2 electrocatalyst was developed via dip-coating/calcination method for oxygen evolution reaction (OER). The catalyst on Ti substrate with a 7/3 molar ratio between Ru and Ir showed the highest electrocatalytic activity for OER among composite samples in different molar ratios. Moreover, the properties of RuO2IrO2 grown on carbon paper were evaluated by proton exchange membrane water electrolysis single cell. Compared with the micron-particle structure of RuO2IrO2 catalyst on the Ti substrate, the catalyst grown on the carbon paper showed a novel nano dendrite shape and can be used directly as the gas diffusion electrode. Owing to the large surface area of the catalyst, the nano dendrite-shaped RuO2IrO2 catalyst exhibits excellent OER performance in the single cell. Furthermore, a cell voltage of 2.50 V is achieved under 200 mA cm−2 at 30 °C by using the optimal composition RuO2IrO2 (Ru: Ir=7/3) and the commercial 20% Pt/C as anode and cathode, respectively.



中文翻译:

具有最佳组成和新颖微观结构的 RuO2IrO2 电催化剂,用于在单电池中析氧

通过浸涂/煅烧方法开发了一种用于析氧反应(OER)的高活性RuO 2 IrO 2电催化剂。在不同摩尔比的复合样品中,Ru和Ir摩尔比为7/3的Ti基底上的催化剂表现出最高的OER电催化活性。此外,通过质子交换膜水电解单电池评估了在碳纸上生长的RuO 2 IrO 2的性能。与RuO 2 IrO 2的微米级粒子结构比较在Ti基底上生长的催化剂,在碳纸上生长的催化剂呈现出新颖的纳米枝晶形状,可直接用作气体扩散电极。由于催化剂的大表面积,纳米枝晶状RuO 2 IrO 2催化剂在单电池中表现出优异的OER性能。此外,通过使用最佳组成 RuO 2 IrO 2 (Ru: Ir=7/3) 和商业 20% Pt/C 作为阳极和阴极,在 200 mA cm -2在 30 °C下实现了 2.50 V 的电池电压, 分别。

更新日期:2022-01-09
down
wechat
bug