当前位置: X-MOL 学术Chem. Eng. Res. Des. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Exhaust gas treatment using MnO2/Mg–Al layered double hydroxide: Assessment of its mixed gas removal performance and regeneration
Chemical Engineering Research and Design ( IF 3.7 ) Pub Date : 2022-01-05 , DOI: 10.1016/j.cherd.2022.01.003
Tomohito Kameda 1 , Yuriko Takahashi 1 , Shogo Kumagai 1 , Yuko Saito 1 , Satoshi Fujita 2 , Ichirou Itou 2 , Tianye Han 2 , Toshiaki Yoshioka 1
Affiliation  

Combustion methods are popularly used to treat acidic exhaust gases to reduce the emission of pollutants. However, exhaust gas treatment can be difficult and expensive, rendering it essential to develop a new treatment process for acidic exhaust gases. In the present study, we investigated the removal of NO from the HCl–SO2–NO mixed gas using MnO2/Mg–Al layered double hydroxide (MnO2/Mg–Al LDH). We analyzed the influence of CO2 gas on the NO removal. Additionally, we regenerated MnO2/Mg–Al LDH after the acid gas adsorption using the wet method and examined the possibility of its cyclical use. MnO2/Mg–Al LDH could simultaneously remove HCl, SO2, and NO from the mixed gas. Because HCl and SO2 influenced the NO removal rate, we proposed a two-step treatment process with MnO2/Mg–Al LDH and CO3•Mg–Al LDH to efficiently remove HCl, SO2, and NO from the HCl–SO2–NO mixed gas. The NO removal rate decreased with an increase in the CO2 concentration, confirming the influence of CO2. Additionally, the results confirmed the possible cyclic use of MnO2/Mg–Al LDH after removing acid gases. However, the Mn elution and Mn(IV) concentration decreased the removal rates of SO2 and NO, respectively. Thus, it is necessary to develop the regeneration method further.



中文翻译:

使用 MnO2/Mg-Al 层状双氢氧化物处理废气:其混合气体去除性能和再生的评估

燃烧法普遍用于处理酸性废气,以减少污染物的排放。然而,废气处理可能既困难又昂贵,因此必须开发一种新的酸性废气处理工艺。在本研究中,我们研究了使用 MnO 2 /Mg-Al 层状双氢氧化物 (MnO 2 /Mg-Al LDH)从 HCl-SO 2 -NO 混合气体中去除 NO 。我们分析了CO 2气体对NO去除的影响。此外,我们使用湿法吸附酸性气体后再生了 MnO 2 /Mg-Al LDH,并检验了其循环使用的可能性。MnO 2 /Mg-Al LDH 可同时去除 HCl、SO 2, 和混合气体中的 NO。由于 HCl 和 SO 2影响 NO 去除率,我们提出了 MnO 2 /Mg-Al LDH 和 CO 3 •Mg-Al LDH的两步处理工艺,以有效去除HCl-SO中的 HCl、SO 2和 NO 2—— NO混合气体。NO去除率随着CO 2浓度的增加而降低,证实了CO 2的影响。此外,结果证实了在去除酸性气体后可能循环使用 MnO 2 /Mg-Al LDH。然而,Mn 洗脱和Mn(IV) 浓度分别降低了SO 2和NO的去除率。因此,有必要进一步发展再生方法。

更新日期:2022-01-11
down
wechat
bug