Kagome metals $A{\mathrm{V}}_3{\mathrm{Sb}}_5$ ($A=\mathrm{K}$, Rb, and Cs) exhibit a unique superconducting ground state coexisting with charge-density wave (CDW), whereas how these characteristics are affected by carrier doping remains unexplored because of the lack of an efficient carrier-doping method. Here we report successful electron doping to ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$ by Cs dosing, as visualized by angle-resolved photoemission spectroscopy. We found that the electron doping with Cs dosing proceeds in an orbital-selective way, as characterized by a marked increase in electron filling of the Sb $5p_z$ and V $3d_{xz/yz}$ bands as opposed to the relatively insensitive nature of the V $3d_{xy/x^2-y^2}$ bands. By monitoring the temperature evolution of the CDW gap around the $\overline{M}$ point, we found that the CDW can be completely killed by Cs dosing while keeping the saddle point with the V $3d_{xy/x^2-y^2}$ character almost pinned at the Fermi level. The present result suggests a crucial role of multiorbital effect to the occurrence of CDW and provides an important step toward manipulating the CDW and superconductivity in $A{\mathrm{V}}_3{\mathrm{Sb}}_5$.

中文翻译：

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Kagome超导体CsV3Sb5中电荷密度波的载流子注入和操纵

可果美金属 $\mathrm{一个}{\mathrm{伏}}_3{锑}_5$ ($\mathrm{一个}=\mathrm{钾}$、Rb 和 Cs) 表现出与电荷密度波 (CDW) 共存的独特超导基态，而由于缺乏有效的载流子掺杂方法，这些特性如何受载流子掺杂的影响仍未得到探索。在这里，我们报告了成功的电子掺杂${\mathrm{电压}}_3{锑}_5$通过 Cs 剂量，如角度分辨光电发射光谱所显示的那样。我们发现 Cs 的电子掺杂以轨道选择性的方式进行，其特征是 Sb 的电子填充显着增加$5p_z$ 和 V $3d_{Xz/是z}$ 与 V 相对不敏感的性质相反 $3d_{X是/X^2-{是}^2}$乐队。通过监测周围的 CDW 间隙的温度演变$\overline{米}$ 点，我们发现 CDW 可以通过 Cs 剂量完全杀死，同时保持鞍点与 V $3d_{X是/X^2-{是}^2}$字符几乎固定在费米能级。目前的结果表明多轨道效应对 CDW 的发生起着至关重要的作用，并为操纵 CDW 和超导性提供了重要的一步。$\mathrm{一个}{\mathrm{伏}}_3{锑}_5$.