This review highlights the most important advances in the development and manufacture of advanced hybrid polymer-inorganic layered anticorrosion coatings for marine applications. These newly hybrid anticorrosion systems are gaining importance with the premise to improve the efficiency of the widely employed pure organic coatings, while widening the available types of polymeric materials employed. These could give rise to innovative high protective coatings with improved characteristics (mechanical strength, conductivity, biodegradability) or secondary functionalities (self-healing, anti-fouling). Through this document, four aspects are mainly overviewed, first, the use of 2D-layered inorganic fillers in coatings based on a barrier-type protection anticorrosion mechanism, with a special focus on graphene and its derivatives. Second, different modification strategies are presented, including covalent and non-covalent, always aiming to increase the compatibility between filler and matrix that would give as a result more efficient systems, due to 2D-layered fillers biggest drawback, their tendency to agglomerate. Third, different multi-functionalizing opportunities that graphene and its derivatives have to offer when introduced to these systems are reviewed, presenting some of the latest works reported in the past 2 to 3 years, while reviewing alternative layered structures such as natural clays or layered double hydroxides with their modifications. Fourth, different possibilities for multifunctioning these systems and their compatibility with graphene-like fillers are discussed. Finally, the conclusions and future perspectives on graphene-based anticorrosion nanocomposites are presented.

本综述重点介绍了用于船舶应用的先进混合聚合物-无机层状防腐涂料的开发和制造方面的最重要进展。这些新的混合防腐系统在提高广泛使用的纯有机涂层的效率的前提下变得越来越重要，同时扩大了所使用的聚合材料的可用类型。这些可能会产生具有改进特性（机械强度、导电性、生物降解性）或次要功能（自修复、防污）的创新高保护涂层。通过该文件，主要概述了四个方面，第一，二维层状无机填料在基于屏障型保护防腐机制的涂料中的应用，特别关注石墨烯及其衍生物。第二，提出了不同的改性策略，包括共价和非共价，总是旨在增加填料和基体之间的相容性，从而提供更有效的系统，由于二维层状填料的最大缺点，它们有团聚的倾向。第三，回顾了石墨烯及其衍生物在引入这些系统时必须提供的不同多功能化机会，展示了过去 2 到 3 年报道的一些最新作品，同时回顾了替代层状结构，如天然粘土或层状双层氢氧化物及其修饰。第四，讨论了使这些系统多功能的不同可能性及其与石墨烯类填料的兼容性。最后，